CHEM 33000 : Physical Chemistry - I

This course will focus on the principles of classical thermodynamics and their application to simple chemical systems. An introduction to statistical thermodynamics will be provided in the last few lectures.

Pre-requisites: CHEM 10401 (General Chemistry II), MATH 20300 (Calculus III) and PHYS 20700 (General Physics)

CUNY Policy on Academic Integrity

The following topics will be covered:
01. Properties of Gases
02. Work and Energy
03. State Functions and Path Functions
04. The First Law of Thermodynamics
05. The Second Law of Thermodynamics
06.The Third Law of Thermodynamics
07. Helmholtz and Gibbs Energies
08. Chemical Equilibria
09. Boltzmann Factor and Partition Functions
10. Partition Function and Ideal Gases

Lecture Notes
Lecture 1
Lecture 2
Sample Problems 1
Solutions to Quiz #1
Lecture 3
Lecture 4
Sample Problems 2
Lecture 5
Solutions to Quiz #2
Sample Problems 3
Lecture 6
Lecture 7
Sample Problems 4
Solutions to Quiz #3
Sample Problems 5
Lecture 8
Additional Problems
Solutions to Quiz #4

Classes

Tuesday, Thursday 9:30-10:45 AM (MR-1307)

Workshop

Friday 9:30 - 10:45 AM (MR-1307)

Office Hours

Tuesday 10:50 - 12:00 PM (MR-1314)

Grading

Midterm - 35%
Final - 35%
Quizzes (best 2 of 4) - 30%
All exams will be open book, open notes.

Texts

The following textbooks are suggested:
(1) Physical Chemistry 7th Edition
Atkins and De Paula

(2) Physical Chemistry - A Molecular Approach
McQuarrie and Simon
(3) Molecular Thermodynamics
McQuarrie and Simon

Announcements

The make-up final examination will be will be held on Tuesday, December 18 from 8-10 AM in the regular classroom.
The final examination will cover lectures 6, 7 & 8.